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Material World
Object

Smartphone

About sixty elements in something the size of a hand — the most materially complex object most people own, and the one they own most casually.

A smartphone contains something in the region of sixty of the ninety or so elements that occur usefully in nature. No other object in ordinary use comes close, and the count is not padding — each one is there because nothing else does its job.

A rough inventory by function. Structure: an aluminium alloy frame or a glass and polymer body, and an aluminosilicate cover glass chemically strengthened by ion exchange. Processor: silicon, with copper interconnect, tungsten vias, cobalt and hafnium in the transistor structures, and a dozen dopants at parts per billion. Display: indium tin oxide for the transparent electrode, and rare earths in the emitters. Battery: lithium, cobalt, graphite, aluminium, copper. Speakers and vibration motor: neodymium, iron, boron, and dysprosium to keep the magnet working when it warms. Capacitors: tantalum, in quantities so small and so essential that the metal became a conflict-minerals category of its own. Circuit board: copper, glass fibre, epoxy, tin, silver, gold.

The gold is worth noting for scale. There is roughly thirty milligrams of it in a phone — pennies' worth — and it is there because gold does not corrode, so a contact plated with it still works in ten years. A tonne of phones contains far more gold than a tonne of ore from any mine on earth.

Why it behaves as it does

Almost every material in a phone is present because of a property that only becomes visible at small scale or long duration.

The cover glass is soda-lime's chemistry with the sodium swapped for potassium at the surface. Potassium ions are larger, so the surface layer is left in compression, and a crack cannot open against compression. That is why a phone screen survives being sat on and shatters when dropped on a corner — a point load reaches past the compressed layer.

The magnets are neodymium-iron-boron with a few per cent of dysprosium or terbium, and the heavy rare earth is there for one reason: coercivity falls with temperature, and a magnet next to a warm processor would otherwise weaken. Perhaps a gram of it, and it is the part of the phone with the sharpest supply concentration.

The capacitors exploit tantalum's oxide, which forms a coherent insulating film only nanometres thick that will hold hundreds of times its own thickness in voltage. That gives more capacitance per cubic millimetre than any competing chemistry, which is why the metal survives in an application where everything else has been miniaturised away.

The battery is the only part of the phone that is consumed rather than used, and it sets the object's life. Everything else would work for decades.

Economic significance

The phone is where four separate raw-material arguments meet, and they are worth separating.

Conflict minerals. Tin, tantalum, tungsten and gold — the 3TG — were the subject of the first serious supply-chain due diligence regime in electronics, driven by armed groups financing themselves from mining in eastern Congo. Section 1502 of Dodd-Frank in 2010 and the EU regulation that followed made smelter-level auditing routine. It is one of the few such regimes with measurable effect and it did not solve the problem.

Cobalt, for the battery, carries the artisanal mining problem that no audit has been able to close.

Rare earths, for the magnets and phosphors, carry a processing concentration rather than a mining one — separation is the hard step and it is overwhelmingly Chinese.

Everything else is simply too dispersed to recover. The recycling arithmetic is stark: gold, silver, copper and palladium are recovered because they pay, and indium, tantalum, gallium and the rare earths mostly are not, because there are milligrams of each in a device that has to be shredded to get at any of it. Well under a fifth of electronic waste is formally recycled worldwide.

And the object's lifetime is a materials decision made elsewhere. A phone replaced after three years has amortised sixty supply chains over three years; the manufacturing footprint dominates the use footprint by a wide margin, so how long it is kept matters more than what it draws from a socket.

Environmental impact

Roughly eighty per cent of a phone's lifetime carbon is emitted before it is switched on, which inverts the intuition that a device's footprint is about its electricity.

That is because the processor is the most energy-intensive manufactured object per gram there is. A wafer fab uses vast quantities of ultrapure water and electricity, and the yield means much of what is made is discarded.

So the honest advice is unglamorous and does not involve buying anything: keep it longer, replace the battery rather than the phone, and pass it on rather than putting it in a drawer. The estimated number of unused phones sitting in drawers worldwide runs into the billions, which is a larger stock of recoverable metal than most mines represent — and it is the reason repairability and battery-replacement rules have become materials policy rather than consumer policy.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is made of

  • Silicon element · the processor, the memory and the image sensor — and the most energy-intensive manufactured material per gram there is
  • Copper element · every interconnect on the chip and every track on the board
  • Gold element · about thirty milligrams, on contacts and bond wires, because a gold-plated contact still works in ten years — a tonne of phones assays richer than a tonne of ore from any mine on earth
  • Tantalum element · in the capacitors, whose oxide film holds hundreds of times its own thickness in voltage — more capacitance per cubic millimetre than anything else, which is why the metal survived miniaturisation
  • Neodymium element · in the speaker, the microphone and the vibration motor, as the magnet alloy
  • Dysprosium element · a few per cent of the magnet, and there for one reason: coercivity falls with temperature and the magnet sits next to a warm processor
  • Lithium element · the battery, and the only part of the phone that is consumed rather than used
  • Cobalt element · the cathode, and the element carrying the supply problem no audit has closed
  • Tin element · the solder on every joint on the board, and one of the four conflict minerals
  • Tungsten element · the vias in the chip, and the mass in the vibration motor — the fourth of the 3TG
  • Indium tin oxide material · the transparent electrode of the touchscreen, which has to conduct and be invisible at the same time — a combination almost nothing offers
  • Soda-lime glass material · as an aluminosilicate cover glass with the surface sodium exchanged for larger potassium, which leaves it in compression — a crack cannot open against compression, which is why a screen survives being sat on
  • 7000 series aluminium alloy alloy · the frame, where stiffness per gram is what is being bought
  • Battery graphite material · the anode, and roughly twice the mass of the cathode
  • Lithium cobalt oxide compound · the cathode, and the small-cell chemistry: highest energy per unit volume, and a few hundred cycles is long enough for a phone
  • Phosphor material · in the display, where rare earth emitters convert the backlight or drive the pixel directly
  • Glass fibre composite material · the board everything else is mounted on, which is a thermoset and therefore the part of the phone that most reliably becomes waste

is used in

  • Electronics manufacture industry · and it is where four separate raw-material arguments meet — the 3TG conflict minerals, cobalt, the rare earths, and everything too dispersed to recover

is associated with

  • The semiconductor era event · the object the whole period arrives at, and the one that put roughly sixty elements into a pocket

is used as

  • Telecommunications application · and the radio front end alone reaches gallium arsenide, gallium nitride and a dozen filters made of piezoelectric ceramic

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)

Questions this page answers

Where it comes from, and what it becomes

Follow Smartphone back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Smartphone → is made of (every interconnect on the chip and every track on the board) → Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (as the element removed, not added) → Oxygen → is produced by (the largest output by tonnage, and the reason air separation units sit beside steelworks) → Air separation → takes as input (the feedstock, and an unusual one in being free, unlimited and available anywhere — the cost is entirely the energy to liquefy it) → Air
  • Smartphone → is made of (the solder on every joint on the board, and one of the four conflict minerals) → Tin → is produced by (reduced from cassiterite at relatively low temperature) → Smelting → takes as input (as the element removed, not added) → Oxygen → is produced by (the largest output by tonnage, and the reason air separation units sit beside steelworks) → Air separation → takes as input (the feedstock, and an unusual one in being free, unlimited and available anywhere — the cost is entirely the energy to liquefy it) → Air
  • Smartphone → is made of (the processor, the memory and the image sensor — and the most energy-intensive manufactured material per gram there is) → Silicon → is produced by (carbothermic reduction of silica with coke in a submerged arc furnace, which is smelting in the strict sense even though no ore is involved) → Smelting → takes as input (as the element removed, not added) → Oxygen → is produced by (the largest output by tonnage, and the reason air separation units sit beside steelworks) → Air separation → takes as input (the feedstock, and an unusual one in being free, unlimited and available anywhere — the cost is entirely the energy to liquefy it) → Air
  • Smartphone → is made of (about thirty milligrams, on contacts and bond wires, because a gold-plated contact still works in ten years — a tonne of phones assays richer than a tonne of ore from any mine on earth) → Gold → is sourced from (a significant share of world gold arrives this way, recovered from copper anode slimes at no mining cost of its own) → Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (as the element removed, not added) → Oxygen → is produced by (the largest output by tonnage, and the reason air separation units sit beside steelworks) → Air separation
  • Smartphone → is made of (the cathode, and the element carrying the supply problem no audit has closed) → Cobalt → is sourced from (much of world supply arrives as a by-product of copper mining rather than from cobalt-first operations) → Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (as the element removed, not added) → Oxygen → is produced by (the largest output by tonnage, and the reason air separation units sit beside steelworks) → Air separation
  • Smartphone → is made of (the battery, and the only part of the phone that is consumed rather than used) → Lithium → is produced by (the majority of world supply, concentrated over a year or more in ponds on the Andean salars from a few hundred parts per million to a few per cent) → Brine evaporation → takes as input (and the pond sequence is run so that the less soluble salts crystallise out first, leaving the sodium chloride to be harvested on its own) → Salt → is sourced from (by solar evaporation, which needs a dry sunny coast and is the cheapest route there is) → Seawater → is composed of (about 96.5 per cent by mass — seawater is 3.5 per cent dissolved solids and the rest of it is this) → Water

These are the most distinct paths back. Smartphone can be traced through others besides.

Downstream — what it becomes

  • Smartphone → is used in (and it is where four separate raw-material arguments meet — the 3TG conflict minerals, cobalt, the rare earths, and everything too dispersed to recover) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Smartphone → is associated with (the object the whole period arrives at, and the one that put roughly sixty elements into a pocket) → The semiconductor era complete chain
  • Smartphone → is used as (and the radio front end alone reaches gallium arsenide, gallium nitride and a dozen filters made of piezoelectric ceramic) → Telecommunications