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Material World
Element · Cu

Copper

A soft, ductile metal with exceptional electrical conductivity, and one of the first metals humans worked.

Copper is a reddish metal, atomic number 29, notable for being one of the very few metals that occurs in nature in a directly usable metallic form. That accident of chemistry is why it was worked long before smelting was understood: native copper could be hammered into shape by people with no metallurgy at all.

Its modern importance rests on a different property. Copper conducts electricity better than any metal except silver, and unlike silver it is abundant enough to wire a planet. Roughly two-thirds of copper production goes into electrical applications.

Why it behaves as it does

Copper conducts electricity well because of the electron it holds most loosely. A copper atom has a single electron outside a filled inner shell, and in the solid those electrons are not attached to particular atoms at all — they occupy states shared across the whole lattice and drift freely when a voltage is applied.

A metal conducts badly when something scatters those moving electrons: impurities, lattice defects, or the vibration of the atoms themselves. Copper is a soft, regular, close-packed lattice of a single element, which gives them comparatively little to collide with. That is also why conductivity falls as copper is warmed, and why alloying it — with zinc to make brass, or with nickel — reduces conductivity sharply while making the metal stronger. Silver is marginally better for the same reasons and costs a great deal more.

Extraction

Most copper is now produced from sulfide ores, chiefly chalcopyrite, at grades well below one percent copper by mass. The ore is crushed, concentrated by froth flotation, then smelted and electrolytically refined to the 99.99% purity that electrical use demands.

The low grades are worth noting: a modern copper mine moves an enormous quantity of rock for each tonne of metal, which is why copper's environmental and energy footprint is dominated by extraction rather than by refining or fabrication.

History

Copper artefacts predate deliberate smelting by millennia. The decisive change came when it was found that adding tin produced bronze — harder, easier to cast, and capable of holding an edge. That discovery defines an archaeological age.

Name origin

From Latin cuprum, itself a contraction of aes Cyprium, 'metal of Cyprus', after the island that supplied much of the Roman world's copper.

Uses

Electrical conduction dominates: copper carries the current in building wiring, motor windings, transformers and the grid itself, because only silver conducts better and silver is not affordable by the tonne. Electrification of transport and generation raises copper demand faster than almost any other metal.

Its other uses follow from corrosion resistance and workability — plumbing tube, roofing and cladding that weathers to a green patina, and heat exchangers. Alloyed, it becomes brass and bronze. Copper surfaces are also genuinely antimicrobial, which has revived interest in copper touch surfaces in hospitals.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is found in

  • Chalcopyrite — mineral Wikidata
  • 7000 series aluminium alloy — alloy · 0–2.6% · in the aerospace grades, adding strength and costing corrosion resistance — which is why the sheet is clad in pure aluminium
  • Weathering steel — alloy · 0.25–0.55% · the principal patina-forming addition
  • Sterling silver — alloy · 7.5% · 7.5 per cent, and it is what hardens the metal and what makes it tarnish
  • Zinc die-casting alloy — alloy · 0–3.3% · a fraction of a per cent, raising strength and hardness
  • Babbitt metal — alloy · 2–8% · forms hard needles that keep the antimony crystals from segregating during casting
  • Azurite — mineral Wikidata
  • Malachite — mineral Wikidata

is a component of

  • Bronze — alloy · 78–95%
  • Brass — alloy · the majority component
  • Solder — alloy · 0–1% · under a per cent, to slow the rate at which the joint dissolves the copper it is sitting on
  • Duralumin — alloy · 3–5% · the element that does the age hardening, and the one that ruins the corrosion resistance
  • Cupronickel — alloy · 60–95% · the majority in every common grade — 90/10 for tubing, 75/25 for coinage
  • Pewter — alloy · 0–3% · a small addition alongside the antimony, and one the guilds specified

is extracted from

  • Chalcopyrite — mineral · the principal copper ore worldwide Wikidata
  • Malachite — mineral · a secondary ore, formed where a copper deposit has weathered Wikidata
  • Azurite — mineral · a minor secondary ore, almost always worked alongside malachite Wikidata

is produced by

  • Smelting — process · as blister copper, refined electrolytically afterwards
  • Solvent extraction and electrowinning — process · roughly a fifth of world production, plated straight from solution at cathode purity without ever being melted

is used as

  • Electrical conduction — application
  • Alloying — application · the base metal of both bronze and brass
  • Telecommunications — application · the telegraph, the telephone pair and the coaxial run, and still the last few hundred metres into most buildings

is an alternative to

  • Aluminium — element · as an electrical conductor, where mass matters more than volume
  • Silver — element · better conductor, roughly two orders of magnitude more expensive
  • Polyvinyl chloride — material · in plumbing: PVC displaced copper for drainage and much of supply on cost and on not corroding, at the price of a lower temperature limit and a material nobody wants to burn
  • Optical fibre — material · in communications, and the substitution is essentially complete over distance: fibre carries more information further with less loss, and copper survives where the cost of digging it out exceeds the benefit

is a source for

  • Cobalt — element · much of world supply arrives as a by-product of copper mining rather than from cobalt-first operations
  • Tellurium — element · recovered from copper refining anode slimes
  • Silver — element · from the anode slimes of copper electrorefining, the same stream the platinum group and the tellurium come out of
  • Gold — element · a significant share of world gold arrives this way, recovered from copper anode slimes at no mining cost of its own
  • Selenium — element · from copper anode slimes, alongside the tellurium it accompanies and closely resembles
  • Arsenic — element · recovered from the flue gases of copper and lead smelting, where it is a contaminant to be captured rather than a product to be sought

is an input to

  • Electrorefining — process · as impure smelted anodes, around 99% copper, which is not pure enough for wire
  • Alloying and melting — process · the base metal of both brass and bronze

is used in

  • Electronics manufacture — industry · interconnect and every circuit board track
  • Energy generation — industry · generation, transmission and distribution — and a grid built on wind and solar needs substantially more of it per unit delivered
  • Smartphone — object · every interconnect on the chip and every track on the board
  • Solar panel — object · the tabbing ribbon between cells and the cabling out of the junction box
  • Printed circuit board — object · the foil bonded to the laminate and etched down to the tracks, and the plating through every hole that joins one layer to another

is associated with

  • Copper Age — event · worked before it was useful — ornament and status first, and the furnace skills that bronze then needed

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
  • US National Library of Medicine · Mixed — aggregated third-party content, rights retained by depositors
  • CRC Press / Taylor & Francis · Commercially published reference work, all rights reserved

Questions this page answers

Where it comes from, and what it becomes

Follow Copper back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (as the element removed, not added) → Oxygen → is produced by (the largest output by tonnage, and the reason air separation units sit beside steelworks) → Air separation → takes as input (the feedstock, and an unusual one in being free, unlimited and available anywhere — the cost is entirely the energy to liquefy it) → Air
  • Copper → is produced by (roughly a fifth of world production, plated straight from solution at cathode purity without ever being melted) → Solvent extraction and electrowinning → takes as input (in the low-grade and oxidised ores that flotation cannot economically treat, with bacteria oxidising the sulfide into a form the acid can attack) → Chalcopyrite
  • Copper → is extracted from (the principal copper ore worldwide) → Chalcopyrite
  • Copper → is extracted from (a secondary ore, formed where a copper deposit has weathered) → Malachite
  • Copper → is extracted from (a minor secondary ore, almost always worked alongside malachite) → Azurite
  • Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (roasted to drive off sulfur, then reduced to copper) → Chalcopyrite

These are the most distinct paths back. Copper can be traced through others besides.

Downstream — what it becomes

  • Copper → is a source for (from the anode slimes of copper electrorefining, the same stream the platinum group and the tellurium come out of) → Silver → is a component of (a few per cent in the lead-free alloys, which measurably raised world silver demand when the transition happened) → Solder → is used in (every joint on it, and tin-silver-copper since RoHS pushed the lead out from 2006) → Printed circuit board → is used in (and it is the change that made electronics manufacturable: assembly stopped being a wiring job and became a printing one) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Copper → is an input to (the base metal of both brass and bronze) → Alloying and melting → produces (tin into copper — the first alloy anybody made deliberately) → Bronze → is used to make (cast in a two-piece mould with a core, which is what bronze does better than the copper it replaced) → Bronze socketed axe → is associated with → Bronze Age complete chain
  • Copper → is a source for (a significant share of world gold arrives this way, recovered from copper anode slimes at no mining cost of its own) → Gold → is used in (about thirty milligrams, on contacts and bond wires, because a gold-plated contact still works in ten years — a tonne of phones assays richer than a tonne of ore from any mine on earth) → Smartphone → is used in (and it is where four separate raw-material arguments meet — the 3TG conflict minerals, cobalt, the rare earths, and everything too dispersed to recover) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Copper → is a component of (under a per cent, to slow the rate at which the joint dissolves the copper it is sitting on) → Solder → is used in (every joint on it, and tin-silver-copper since RoHS pushed the lead out from 2006) → Printed circuit board → is used in (and it is the change that made electronics manufacturable: assembly stopped being a wiring job and became a printing one) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Copper → is a component of → Bronze → is used to make (cast in a two-piece mould with a core, which is what bronze does better than the copper it replaced) → Bronze socketed axe → is associated with → Bronze Age complete chain
  • Copper → is a source for (much of world supply arrives as a by-product of copper mining rather than from cobalt-first operations) → Cobalt → is a component of (a substantial addition, and one of the reasons aviation and battery demand compete for the same metal) → Nickel superalloy → is associated with (the jet engine created the industry, because no existing material survived the turbine inlet) → The wartime materials programmes complete chain

These are the most distinct paths onward. Copper ends up in others besides.