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Material World
Element · Sn

Tin

A soft, low-melting metal whose main historical significance is that adding it to copper makes bronze.

Tin is a soft, silvery metal that melts at a temperature a good campfire can reach. On its own it is too weak to be structurally useful, and it has never been an important structural metal.

Its significance is almost entirely as an alloying element. A small proportion of tin transforms copper into bronze, and the scarcity and geographical concentration of tin ore is one of the reasons Bronze Age trade networks stretched as far as they did.

History

Tin deposits are far rarer and more localised than copper deposits. Cornwall, Iberia and Central Asia were the significant western sources, and the long-distance movement of tin is among the earliest evidence for organised international trade.

Uses

Solder is the largest use, and it changed shape rather than shrinking: lead-free solders required more tin, not less, so restricting lead raised tin consumption. Nearly all electronics are held together by tin alloy joints.

Tinplate — steel with a thin tin coating — is what a tin can actually is, the tin providing a non-toxic corrosion barrier over the steel that provides the strength. Tin chemicals stabilise PVC against heat and light, and tin remains the element that makes bronze bronze, the alloy that gave an age its name.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is found in

  • Cassiterite mineral Wikidata
  • Indium tin oxide material · the dopant, at perhaps a tenth of the indium — it is what supplies the free electrons that make the film conduct Wikidata
  • Babbitt metal alloy · 0–91% · the matrix of the tin-based grades, which are the ones modern specifications call for

is a component of

  • Bronze alloy · 5–22% · the component that hardens the copper and lowers its melting point
  • Solder alloy · 60–99% · the base of every solder in current use, leaded or not
  • Amalgam alloy · 8–15% · in the dental alloy, controlling how fast the mixture sets
  • Pewter alloy · 85–99% · almost all of it; the rest is there to stop it being too soft to hold a shape

is extracted from

  • Cassiterite mineral · the only tin ore of economic importance Wikidata

is produced by

  • Smelting process · reduced from cassiterite at relatively low temperature

is used as

  • Alloying application · the addition that turns copper into bronze

is produced at

  • Cornwall place · from antiquity until 1998

is an input to

is an alternative to

  • Lead element · in solder: lead-free solders are tin-based, melt hotter, and were adopted under regulation rather than on performance

is used in

  • Smartphone object · the solder on every joint on the board, and one of the four conflict minerals

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
  • US National Library of Medicine · Mixed — aggregated third-party content, rights retained by depositors
  • CRC Press / Taylor & Francis · Commercially published reference work, all rights reserved

Questions this page answers

Where it comes from, and what it becomes

Follow Tin back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Tin → is produced by (reduced from cassiterite at relatively low temperature) → Smelting → takes as input (as the element removed, not added) → Oxygen → is produced by (the largest output by tonnage, and the reason air separation units sit beside steelworks) → Air separation → takes as input (the feedstock, and an unusual one in being free, unlimited and available anywhere — the cost is entirely the energy to liquefy it) → Air
  • Tin → is extracted from (the only tin ore of economic importance) → Cassiterite
  • Tin → is produced by (reduced from cassiterite at relatively low temperature) → Smelting → takes as input (roasted to drive off sulfur, then reduced to copper) → Chalcopyrite
  • Tin → is produced by (reduced from cassiterite at relatively low temperature) → Smelting → takes as input (reduced with carbon to metallic tin) → Cassiterite
  • Tin → is produced by (reduced from cassiterite at relatively low temperature) → Smelting → takes as input (reduced with coke in a blast furnace) → Hematite
  • Tin → is produced by (reduced from cassiterite at relatively low temperature) → Smelting → takes as input (the phosphate rock charged to the electric furnace, with coke to reduce it and silica to take up the calcium) → Apatite

These are the most distinct paths back. Tin can be traced through others besides.

Downstream — what it becomes

  • Tin → is an input to (the addition that hardens copper into bronze) → Alloying and melting → produces (tin into copper — the first alloy anybody made deliberately) → Bronze → is used to make (cast in a two-piece mould with a core, which is what bronze does better than the copper it replaced) → Bronze socketed axe → is associated with → Bronze Age complete chain
  • Tin → is a component of (the base of every solder in current use, leaded or not) → Solder → is used in (every joint on it, and tin-silver-copper since RoHS pushed the lead out from 2006) → Printed circuit board → is used in (and it is the change that made electronics manufacturable: assembly stopped being a wiring job and became a printing one) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Tin → is a component of (the component that hardens the copper and lowers its melting point) → Bronze → is used to make (cast in a two-piece mould with a core, which is what bronze does better than the copper it replaced) → Bronze socketed axe → is associated with → Bronze Age complete chain
  • Tin → is used in (the solder on every joint on the board, and one of the four conflict minerals) → Smartphone → is used in (and it is where four separate raw-material arguments meet — the 3TG conflict minerals, cobalt, the rare earths, and everything too dispersed to recover) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Tin → is a component of (almost all of it; the rest is there to stop it being too soft to hold a shape) → Pewter → is used as (the reason it existed: cast cheaply on a domestic hearth, cleanable, and recastable when it dented — the tableware of ordinary European households for five centuries) → Tableware and vessels
  • Tin → is used as (the addition that turns copper into bronze) → Alloying

These are the most distinct paths onward. Tin ends up in others besides.