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Material World
Compound · H2O

Water

The most used substance on earth, and the one whose every important property is an exception to what a molecule that small should do.

Water is a molecule of three atoms, and by the ordinary rules for a molecule that small it should be a gas at room temperature. Hydrogen sulfide, its exact structural analogue one row down the periodic table, boils at −60 °C. Water boils at 100. The 160-degree discrepancy is the single fact from which almost everything else about water follows, and the reason a planet covered in it has a liquid ocean rather than an atmosphere of steam.

It is also the substance industry uses more of than any other, by a margin nothing approaches. It is the solvent every leaching, flotation and electrowinning process runs in, the working fluid of essentially all thermal power generation, the coolant of most of the rest, and about a sixth of a concrete mix by volume.

Why it behaves as it does

The oxygen atom pulls the shared electrons hard, and the molecule is bent rather than linear, so one end carries a partial negative charge and the other two a partial positive. Each molecule can therefore hold hands with four neighbours — two through its own hydrogens, two through its lone pairs — and a hydrogen bond is roughly a twentieth the strength of a covalent bond but there are a great many of them.

Every anomaly is a consequence of that network.

It boils far too high, because escaping into vapour means breaking those bonds and not merely overcoming the weak attractions a molecule of its size would otherwise have.

Ice floats. The tetrahedral network in ice is more open than the jostling arrangement in liquid water, so the solid is about 9 per cent less dense than the liquid — and water reaches its maximum density at 4 °C rather than at freezing. Almost every other substance is denser as a solid and sinks. Lakes therefore freeze downward from the surface and do not freeze solid, which is not a small point about how life gets through a winter.

Its heat capacity is enormous, higher per gram than nearly anything else, because heat goes into breaking bonds rather than into motion. This is why the sea moderates climate, why water is the coolant of choice, and why the latent heat of vaporisation is large enough that sweating works.

Its surface tension is the highest of any ordinary liquid except mercury, which is what draws sap up a tree and holds a drop together.

It dissolves more kinds of thing than any other solvent, because the same polarity that lets it bond to itself lets it surround an ion and pull it away from its lattice. That is the property mineral processing is built on, and it is also the reason water is never found pure outside a laboratory.

Uses

As a reactant it is consumed rather than borrowed: in cement hydration, which is what makes concrete set and is not drying; in the hydration of ethylene to ethanol; in steam reforming, where it supplies the hydrogen for most of the world's ammonia.

As a solvent it is the medium of every hydrometallurgical route here — froth flotation, cyanidation, solvent extraction and electrowinning, the Bayer liquor, chlor-alkali brine.

As a working fluid it runs the thermal power cycle. Coal, gas, nuclear and concentrated solar all do the same thing at bottom: boil water, expand the steam through a turbine, condense it, repeat. That choice is made on water's latent heat and heat capacity, and no other cheap fluid comes close.

As a coolant it takes heat away from engines, reactors, machine tools and data centres, and its capacity here is why data-centre water consumption became a public argument.

And as the thing itself it is drunk, and drinking water is the least of it by volume: agriculture takes roughly seventy per cent of human freshwater withdrawal and industry most of the rest.

Environmental impact

Water is not scarce and fresh water in the right place at the right time very often is, and conflating the two is the commonest error in the subject. About 2.5 per cent of the world's water is fresh, and most of that is locked in ice or deep groundwater.

The industrial questions are three, and they are different from one another.

Withdrawal against consumption. A power station withdraws enormous volumes and returns nearly all of it, warmer. An irrigated field consumes what it takes. A figure quoted without saying which is being measured is not informative, and both are routinely quoted as though they were the same number.

Aquifer depletion, where extraction exceeds recharge on a timescale of decades — the Ogallala, the North China Plain, the Punjab — and the water being used is effectively a mineral deposit rather than a renewable flow.

Contamination, which is where mining and chemicals sit. Acid mine drainage, tailings seepage, tannery chromium and PFAS all take water that was fine and make it not, and the volume affected is generally far larger than the volume used.

Desalination answers scarcity where energy is cheap and coastline is available, at a real energy cost and with a hypersaline brine to dispose of. It is a genuine solution to a local problem and not a general one.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

contains

  • Hydrogen element · two atoms of it, and eleven per cent of the mass
  • Oxygen element · one atom, and eighty-nine per cent of the mass — which is why water is heavy for a molecule so small

is sourced from

  • Seawater material · by desalination, where energy is cheap and coastline available — the only route that adds fresh water rather than moving it

is a component of

  • Seawater material · about 96.5 per cent by mass — seawater is 3.5 per cent dissolved solids and the rest of it is this
  • Concrete material · 14–18% · and it is consumed rather than dried off: cement sets by hydration, which is a chemical reaction with this water, and concrete cured under water is stronger than concrete left in the air

is an input to

  • Froth flotation process · the medium the whole separation happens in — a slurry of ground ore in water, with air blown through it
  • Cyanidation process · as the leach solution: the cyanide is a few hundred parts per million and the rest is water
  • Kraft pulping process · and the pulp and paper industry is among the largest industrial water users there is
  • Chlor-alkali electrolysis process · as the brine the cell electrolyses, and as the source of the hydrogen that comes off the cathode
  • Hydration process · consumed into the product rather than evaporated from it, and the water-to-cement ratio is the single most important number in concrete — and the one most often quietly increased on site

is used in

  • Energy generation industry · the working fluid of essentially all thermal generation — coal, gas, nuclear and concentrated solar all boil water and expand the steam through a turbine
  • Construction industry · for concrete, which consumes it chemically, and for the far larger volumes used washing aggregate and suppressing dust
  • Mining and quarrying industry · and the industry's water use is mostly a contamination question rather than a consumption one — acid drainage and tailings seepage affect far more water than any operation withdraws
  • Chemical manufacture industry · as solvent, reactant and coolant, and as the steam that reforms methane into the hydrogen for most of the world's ammonia

is a source for

  • Peat material · waterlogging is the whole mechanism: a bog is anoxic below a few centimetres, so the organisms that would decompose the plant matter cannot work, and it accumulates instead

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)

Questions this page answers

Where it comes from, and what it becomes

Follow Water back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Water → is sourced from (by desalination, where energy is cheap and coastline available — the only route that adds fresh water rather than moving it) → Seawater

Downstream — what it becomes

  • Water → is an input to (as the leach solution: the cyanide is a few hundred parts per million and the rest is water) → Cyanidation → produces (from ore containing a few grams per tonne, far below what panning could recover) → Gold → is used in (about thirty milligrams, on contacts and bond wires, because a gold-plated contact still works in ten years — a tonne of phones assays richer than a tonne of ore from any mine on earth) → Smartphone → is used in (and it is where four separate raw-material arguments meet — the 3TG conflict minerals, cobalt, the rare earths, and everything too dispersed to recover) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Water → is an input to (and the pulp and paper industry is among the largest industrial water users there is) → Kraft pulping → produces (as tall oil rosin from the black liquor — a by-product of making paper, and now a larger source than tapping) → Resin → is used in (as the flux in rosin-cored solder wire: it strips the oxide off copper at soldering temperature so the solder can wet the metal, and the smell of soldering is the smell of pine) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Water → is an input to (consumed into the product rather than evaporated from it, and the water-to-cement ratio is the single most important number in concrete — and the one most often quietly increased on site) → Hydration → produces (it does not dry — the calcium silicates react with the mix water and grow an interlocking hydrate gel, which is why it sets under water and must be kept wet to reach strength) → Concrete → is a component of (with steel put where the tension is) → Reinforced concrete → is associated with (after it rather than during — Portland cement is 1824 and reinforcement is the 1860s onward, and the Romans had concrete with no reinforcement at all) → Industrial Revolution complete chain
  • Water → is a component of (and it is consumed rather than dried off: cement sets by hydration, which is a chemical reaction with this water, and concrete cured under water is stronger than concrete left in the air) → Concrete → is a component of (with steel put where the tension is) → Reinforced concrete → is associated with (after it rather than during — Portland cement is 1824 and reinforcement is the 1860s onward, and the Romans had concrete with no reinforcement at all) → Industrial Revolution complete chain
  • Water → is an input to (the medium the whole separation happens in — a slurry of ground ore in water, with air blown through it) → Froth flotation → is used in (the process that made low-grade disseminated sulfide deposits economic, and therefore made the modern copper industry) → Mining and quarrying → is associated with (steam pumping allowed mines below the water table, which is what made deep coal possible) → Industrial Revolution complete chain
  • Water → is used in (and the industry's water use is mostly a contamination question rather than a consumption one — acid drainage and tailings seepage affect far more water than any operation withdraws) → Mining and quarrying → is associated with (steam pumping allowed mines below the water table, which is what made deep coal possible) → Industrial Revolution complete chain

These are the most distinct paths onward. Water ends up in others besides.