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Material World
Alloy

Tool steel

Steel that cuts, forms or shapes other materials — hard enough to hold an edge and tough enough not to shatter, which are opposing requirements.

Tool steels are carbon steels with enough alloying — chromium, molybdenum, tungsten, vanadium — to be hardened deeply and reliably, and to hold that hardness. They exist to work other materials: to cut, punch, form, mould and shear.

The design problem is that hardness and toughness pull against each other. A cutting edge needs hardness or it deforms; a punch needs toughness or it snaps. There is no steel that maximises both, so the family is a set of compromises with names, and choosing between them is choosing which failure to accept.

All of them are supplied soft, machined, and then hardened — because a steel hard enough to cut with cannot itself be cut. Everything about how a tool is made follows from that ordering.

Processing

Machined or ground in the annealed condition, then hardened by heating to austenitising temperature and quenching, then tempered — always tempered, because an untempered quenched tool steel is brittle enough to crack on its own as residual stress relaxes.

The quench medium is part of the grade. Water-hardening steels are cheap and distort or crack readily; oil-hardening are the general workshop compromise; air-hardening steels move so little in heat treatment that a finished tool can be hardened without needing to be re-ground, which is why they dominate precision tooling.

Cryogenic treatment after quenching converts retained austenite that the quench left behind, and gives a small but real gain in hardness and dimensional stability.

Uses

Cutting tools, punches and dies for sheet metal, injection moulds and die-casting dies, shear blades, thread-rolling dies, chisels and hand tools, and the moulds plastic products are made in.

Mould tooling is the largest use by value and the least visible. An injection mould is a precisely machined, polished, hardened tool steel assembly that costs as much as a house and produces millions of parts, and it is the reason plastic products are cheap.

History

Crucible steel from Benjamin Huntsman in the 1740s is the beginning of tool steel as a controlled material: melting the metal fully gave a uniform composition that cementation steel never had, and Sheffield built an industry on it.

Robert Mushet's air-hardening tungsten steel in 1868 is the first true alloy tool steel, and the ancestor of high-speed steel. Before it, machining speed was limited by the tool losing its temper.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

contains

  • Iron element · 80–97% · the balance
  • Carbon element · 0.3–2.5% · the element that makes hardening possible at all — below about 0.3 per cent no useful martensite forms
  • Chromium element · 0.5–13% · forms hard carbides and deepens hardening, so a thick section hardens through rather than only at the surface
  • Molybdenum element · 0–5% · hardenability and hot strength
  • Vanadium element · 0–4% · forms the hardest carbides of any of them, which is what gives wear resistance

is an input to

  • Heat treatment process · the entire point of the family — supplied soft, machined, then hardened and tempered, because a steel hard enough to cut with cannot itself be cut

is used as

  • Abrasive application · as the tool rather than the abrasive — cutting, punching and forming everything else

succeeded

  • Wootz steel alloy · crucible steel in Sheffield from the 1740s produced a uniform steel by a repeatable process, which is what wootz had achieved by an ore and a tradition and could not be taught

was succeeded by

  • High-speed steel alloy · in machining, and the change was structural: existing machine tools were not stiff enough to use the new steel and the industry rebuilt its product line around it

is produced at

  • Sheffield place · crucible steel from the 1740s, which made the town the centre of the European tool and cutlery trade for a century and a half

is produced by

  • Alloying and melting process · carbon and carbide formers into iron, and the carbide is the working part

Sources

  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
  • Material World
    Our own writing

Questions this page answers

Where it comes from, and what it becomes

Follow Tool steel back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Tool steel → is produced by (carbon and carbide formers into iron, and the carbide is the working part) → Alloying and melting → takes as input (the base metal of both brass and bronze) → Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (as the element removed, not added) → Oxygen → is produced by (the largest output by tonnage, and the reason air separation units sit beside steelworks) → Air separation
  • Tool steel → is produced by (carbon and carbide formers into iron, and the carbide is the working part) → Alloying and melting → takes as input (the base metal of both brass and bronze) → Copper → is extracted from (the principal copper ore worldwide) → Chalcopyrite
  • Tool steel → is produced by (carbon and carbide formers into iron, and the carbide is the working part) → Alloying and melting → takes as input (the base metal of both brass and bronze) → Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (roasted to drive off sulfur, then reduced to copper) → Chalcopyrite
  • Tool steel → is produced by (carbon and carbide formers into iron, and the carbide is the working part) → Alloying and melting → takes as input (the base metal of both brass and bronze) → Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (reduced with carbon to metallic tin) → Cassiterite
  • Tool steel → is produced by (carbon and carbide formers into iron, and the carbide is the working part) → Alloying and melting → takes as input (the base metal of both brass and bronze) → Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (reduced with coke in a blast furnace) → Hematite
  • Tool steel → is produced by (carbon and carbide formers into iron, and the carbide is the working part) → Alloying and melting → takes as input (the base metal of both brass and bronze) → Copper → is produced by (as blister copper, refined electrolytically afterwards) → Smelting → takes as input (the phosphate rock charged to the electric furnace, with coke to reduce it and silica to take up the calcium) → Apatite

These are the most distinct paths back. Tool steel can be traced through others besides.

Downstream — what it becomes

  • Tool steel → is an input to (the entire point of the family — supplied soft, machined, then hardened and tempered, because a steel hard enough to cut with cannot itself be cut) → Heat treatment → produces (the same, and mostly without the autoclave, which is why it costs a fraction as much) → Glass fibre composite → is used in (the FR-4 laminate itself: woven glass cloth in flame-retardant epoxy, stiff, dimensionally stable when heated, and self-extinguishing) → Printed circuit board → is used in (and it is the change that made electronics manufacturable: assembly stopped being a wiring job and became a printing one) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Tool steel → is produced at (crucible steel from the 1740s, which made the town the centre of the European tool and cutlery trade for a century and a half) → Sheffield → is associated with (Bessemer built his first steelworks here in 1858, at the point iron gave way to steel) → Industrial Revolution complete chain
  • Tool steel → is used as (as the tool rather than the abrasive — cutting, punching and forming everything else) → Abrasive
  • Tool steel → is an input to (the entire point of the family — supplied soft, machined, then hardened and tempered, because a steel hard enough to cut with cannot itself be cut) → Heat treatment → produces (laid up as fibre and resin and cured under heat and pressure, usually in an autoclave — and the cure schedule is as much of the specification as the fibre is) → Carbon fibre composite → is used as (aircraft primary structure since the 1990s, where stiffness per unit mass is what is being bought) → Structural engineering
  • Tool steel → is an input to (the entire point of the family — supplied soft, machined, then hardened and tempered, because a steel hard enough to cut with cannot itself be cut) → Heat treatment → is used in (gears, shafts and springs, and case hardening to give a gear a hard face and a tough core) → Automotive manufacture
  • Tool steel → is an input to (the entire point of the family — supplied soft, machined, then hardened and tempered, because a steel hard enough to cut with cannot itself be cut) → Heat treatment → produces (laid up as fibre and resin and cured under heat and pressure, usually in an autoclave — and the cure schedule is as much of the specification as the fibre is) → Carbon fibre composite → is used in (primary structure — a modern wide-body wing and fuselage are more composite than metal) → Aerospace manufacture

These are the most distinct paths onward. Tool steel ends up in others besides.