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Material World
Mineral · Ca5(PO4)3(F,Cl,OH)

Apatite

Mohs 5, the mineral phosphate rock is made of, and the mineral bones and teeth are made of — the same compound doing both jobs.

Apatite is a calcium phosphate, and it is the mineral of two apparently unrelated industries: fertiliser and bone. The hard tissue of vertebrates is a poorly crystalline form of it, and so is the rock mined by the hundred million tonnes to feed crops.

Phosphorus has no substitute in agriculture and no atmospheric reservoir to draw on, unlike nitrogen. That makes apatite one of the few minerals whose supply is a genuine constraint on the food system rather than a matter of price.

How to identify it

Apatite is defined as hardness 5 and is best identified by that: it scratches glass poorly or not at all, and is easily scratched by a knife. Its name comes from the Greek for deceit, because it was so often mistaken for other minerals.

Crystals are hexagonal prisms, commonly green or blue-green, sometimes gemmy enough to be cut.

Uses

Almost all mined apatite is treated with sulfuric acid to make phosphoric acid and superphosphate fertiliser. That single use dominates every other by orders of magnitude.

Smaller quantities go into phosphates for detergents, food additives and animal feed. Gem-quality crystals are cut, but the mineral is too soft for jewellery that will be worn hard.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is an ore of

  • Phosphorus element · essentially all phosphorus, and phosphorus has no substitute in agriculture

is a component of

  • Carbonatite rock · abundant enough in some bodies to be mined for phosphate in its own right
  • Granite rock · the phosphate accessory, present in almost every granite and rarely in quantity
  • Ivory material · 65–75% · carbonated hydroxyapatite, around 70 per cent by mass, in a collagen matrix — the same recipe as bone, arranged without the pores
  • Bone material · 60–70% · carbonated hydroxyapatite in crystals a few nanometres thick — small enough to contain no flaw big enough to start a crack, which is most of why bone is tough

is an input to

  • Froth flotation process · the step that makes phosphate rock into fertiliser feed by removing the carbonate and silica around it
  • Smelting process · the phosphate rock charged to the electric furnace, with coke to reduce it and silica to take up the calcium

is a source for

  • Lithium iron phosphate compound · for the phosphate, by way of phosphoric acid — the same rock that makes fertiliser, and there is a great deal of it

contains

  • Calcium element
  • Chlorine element · substitutes within a solid solution — an individual specimen may hold little of it
  • Fluorine element · substitutes within a solid solution — an individual specimen may hold little of it
  • Hydrogen element · substitutes within a solid solution — an individual specimen may hold little of it
  • Oxygen element
  • Phosphorus element

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)

Questions this page answers

Where it comes from, and what it becomes

Follow Apatite back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Downstream — what it becomes

  • Apatite → is an input to (the phosphate rock charged to the electric furnace, with coke to reduce it and silica to take up the calcium) → Smelting → produces (as blister copper, refined electrolytically afterwards) → Copper → is a component of → Bronze → is used to make (cast in a two-piece mould with a core, which is what bronze does better than the copper it replaced) → Bronze socketed axe → is associated with → Bronze Age complete chain
  • Apatite → is a component of (the phosphate accessory, present in almost every granite and rarely in quantity) → Granite → is a source for (quarried in blocks for cladding, kerbs and monuments) → Dimension stone → is used in (quarried rather than mined, and the distinction is legal and technical rather than merely a word) → Mining and quarrying → is associated with (steam pumping allowed mines below the water table, which is what made deep coal possible) → Industrial Revolution complete chain
  • Apatite → is a source for (for the phosphate, by way of phosphoric acid — the same rock that makes fertiliser, and there is a great deal of it) → Lithium iron phosphate → is used in (in more than half of world cell production, and in almost all stationary storage — the cathode chosen where mass does not bind and price and fire risk do) → Lithium-ion cell → is used in (and portable computing came first by two decades) → Electronics manufacture → is associated with (and the supply chain it produced is the deepest and most concentrated in the world economy) → The semiconductor era complete chain
  • Apatite → is an input to (the step that makes phosphate rock into fertiliser feed by removing the carbonate and silica around it) → Froth flotation → is used in (the process that made low-grade disseminated sulfide deposits economic, and therefore made the modern copper industry) → Mining and quarrying → is associated with (steam pumping allowed mines below the water table, which is what made deep coal possible) → Industrial Revolution complete chain
  • Apatite → is a component of (carbonated hydroxyapatite in crystals a few nanometres thick — small enough to contain no flaw big enough to start a crack, which is most of why bone is tough) → Bone → is an input to (at around 1,000 °C, which burns off the collagen and leaves bone ash — essentially pure calcium phosphate) → Calcination → produces (the solid residue once carbon dioxide has been driven off) → Quicklime → is a component of (as calcium oxide within the clinker phases, not as free lime) → Portland cement → is used in → Construction
  • Apatite → is an ore of (essentially all phosphorus, and phosphorus has no substitute in agriculture) → Phosphorus → is used as (the P in N-P-K, and the one with no chemical substitute) → Fertiliser

These are the most distinct paths onward. Apatite ends up in others besides.