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Material World
Rock

Evaporite

Rock precipitated where a body of salt water dried up — the source of table salt, of potash fertiliser, of gypsum for plaster, and of borates.

An evaporite is what remains when a body of salt water evaporates faster than it is replenished. The salts dissolved in it come out of solution and accumulate as rock, and because different salts saturate at different concentrations they come out in a predictable order — which makes an evaporite sequence readable as a record of how far the drying went.

The economic consequence is that four unrelated industries draw on one rock type. Table salt, potash fertiliser, plasterboard and the borates used in glass and detergent all come out of evaporite deposits, and often out of the same basin at different levels.

How it forms

The sequence follows solubility. Carbonates precipitate first, then gypsum and anhydrite as the water reduces to roughly a fifth of its original volume, then halite, and finally the potassium and magnesium salts — sylvite and carnallite — which need the brine concentrated to a few per cent of where it started. Reaching that last stage requires near-total desiccation, which is why potash deposits are far rarer than salt ones.

The volumes involved are difficult to produce by evaporating a lake once. A metre of halite requires tens of metres of seawater, so the great deposits record basins repeatedly refilled and re-evaporated over long periods — most dramatically the Messinian salinity crisis, when the Mediterranean is thought to have dried almost completely and left kilometre-scale salt beneath its floor.

Salt also flows. Buried under later sediment it deforms plastically and rises as domes, and those domes trap oil against their flanks — which is why salt geology and petroleum geology have been intertwined since the beginning of both.

Economic significance

Salt was the first mineral commodity to be traded at scale and taxed as a matter of state policy, and evaporite basins have shaped settlement patterns accordingly — Salzburg, Hallstatt, Cheshire, the Punjab.

Potash matters differently. Potassium is one of the three macronutrients a crop removes from soil and must have returned, and there is no substitute for it: nitrogen can be fixed from the air and phosphorus recovered from several sources, but potassium comes from evaporite. A handful of basins in Canada, Russia and Belarus hold most of what is accessible, which makes fertiliser supply a geological fact before it is a political one.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is composed of

  • Gypsum mineral · 5–40% · precipitated early, when the water has reduced to roughly a fifth of its volume
  • Halite mineral · 30–90% · the bulk of most evaporite sequences, and the reason the rock is called salt
  • Sylvite mineral · one of the last salts to precipitate, needing near-total desiccation — which is why potash deposits are far rarer than salt ones
  • Borax mineral · in the continental playa evaporites rather than the marine ones, where borate-rich springs fed a closed basin

is sourced from

  • Seawater material · what is left when a body of seawater evaporates faster than it is replenished — the salts come out in order of solubility, which is why the sequence is readable

is a source for

  • Salt compound · mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway

Sources

  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
  • Material World
    Our own writing

Questions this page answers

Where it comes from, and what it becomes

Follow Evaporite back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Evaporite → is sourced from (what is left when a body of seawater evaporates faster than it is replenished — the salts come out in order of solubility, which is why the sequence is readable) → Seawater → is composed of (about 96.5 per cent by mass — seawater is 3.5 per cent dissolved solids and the rest of it is this) → Water
  • Evaporite → is composed of (precipitated early, when the water has reduced to roughly a fifth of its volume) → Gypsum
  • Evaporite → is composed of (the bulk of most evaporite sequences, and the reason the rock is called salt) → Halite
  • Evaporite → is composed of (one of the last salts to precipitate, needing near-total desiccation — which is why potash deposits are far rarer than salt ones) → Sylvite
  • Evaporite → is composed of (in the continental playa evaporites rather than the marine ones, where borate-rich springs fed a closed basin) → Borax

Downstream — what it becomes

  • Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the cathode, in fixed proportion to the chlorine whether demand agrees or not) → Sodium hydroxide → is an input to (hot concentrated caustic soda dissolves the aluminium hydroxides) → Bayer process → produces (crystallised from the liquor and calcined, ready for the smelter) → Aluminium oxide
  • Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the anode) → Chlorine → is an input to (converts the ore to a distillable tetrachloride, which is how the purification is done) → Kroll process → produces (as sponge, which must then be crushed, melted and cast before it is usable metal) → Titanium
  • Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the cathode, in fixed proportion to the chlorine whether demand agrees or not) → Sodium hydroxide → is an input to (with sodium sulfide, breaks the lignin into fragments soluble in the alkaline liquor) → Kraft pulping → produces (via pulp — most chemical pulp and therefore most quality paper) → Paper
  • Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the cathode, in fixed proportion to the chlorine whether demand agrees or not) → Sodium hydroxide → is used as (in the Bayer process and in metal cleaning before coating) → Corrosion protection
  • Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the cathode, in fixed proportion to the chlorine whether demand agrees or not) → Sodium hydroxide → is used in (and it is made as the inseparable co-product of chlorine, which ties the markets for two unrelated chemicals together permanently) → Chemical manufacture
  • Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the anode) → Chlorine → is used as (chlor-alkali production underpins much of industrial chemistry) → Catalysis

These are the most distinct paths onward. Evaporite ends up in others besides.