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Material World
Mineral · NaCl

Halite

Rock salt — the only mineral people eat, and for much of history a commodity worth fighting over.

Foodstuff Ore

Halite is sodium chloride, and it is the one mineral that is a dietary necessity. Human physiology requires sodium and cannot store much of it, which made salt a genuine strategic commodity: taxed, fought over, used as payment, and the reason for the location of a good many old roads and towns.

It is also the textbook example of ionic bonding. Sodium and chlorine alternate in a cubic lattice, and the crystal cleaves along three planes at right angles — smash a piece of rock salt and the fragments are small cubes, which few other minerals do so unambiguously.

How to identify it

It tastes of salt, which is conclusive and is one of the few places in mineralogy where taste is an accepted test. Short of that: cubic cleavage, softness, and solubility in water — halite is one of very few common minerals that simply dissolves.

It is usually colourless or white, but impurities and radiation damage produce yellow, pink and a deep blue that is genuinely striking and entirely a defect in the lattice rather than a chemical difference.

Uses

Most salt produced is never eaten. The chemical industry consumes the majority as feedstock for chlorine and sodium hydroxide, which between them lead to PVC, solvents, paper, soap and a large share of industrial chemistry.

De-icing roads is the next largest use in cold countries, and it is seasonal enough to dominate winter freight in some regions. Food use — seasoning, and preservation by drawing water out of tissue faster than bacteria can tolerate — is small by tonnage and disproportionately large in history.

How it forms

Halite is an evaporite, precipitating when a body of saline water dries up. Because it is among the last salts to come out of solution, thick halite beds mean a basin evaporated almost completely — the Mediterranean did so repeatedly, leaving salt layers a kilometre thick beneath the seabed.

Buried halite behaves unusually: it is less dense than the rock above it and flows slowly under pressure, rising as salt domes that pierce overlying strata. Those domes trap oil and gas against their flanks, which is why salt geology and petroleum geology are closely connected.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is an ore of

  • Sodium element · the same electrolysis; sodium metal is made from molten salt rather than brine Wikidata
  • Chlorine element · by electrolysis of brine, which yields chlorine and sodium hydroxide together Wikidata

is a source for

  • Sodium hydroxide compound · electrolysis of brine, which produces chlorine in fixed proportion

is an input to

is commonly confused with

  • Sylvite mineral · cubic, colourless and found together; sylvite tastes bitter where halite is simply salty

is a component of

  • Evaporite rock · 30–90% · the bulk of most evaporite sequences, and the reason the rock is called salt

has the same composition as

  • Salt compound · the same substance in two trades: halite is a cubic mineral with a cleavage and a type locality, and salt is a food, a de-icer and the feedstock of the chlorine industry

contains

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
  • COD Advisory Board / Vilnius University · CC0 — contributors place data in the public domain

Questions this page answers

Where it comes from, and what it becomes

Follow Halite back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Downstream — what it becomes

  • Halite → is an ore of (by electrolysis of brine, which yields chlorine and sodium hydroxide together) → Chlorine → is an input to (converts the ore to a distillable tetrachloride, which is how the purification is done) → Kroll process → produces (as sponge, which must then be crushed, melted and cast before it is usable metal) → Titanium → is a component of (the other half of the strengthening phase) → Nickel superalloy → is associated with (the jet engine created the industry, because no existing material survived the turbine inlet) → The wartime materials programmes complete chain
  • Halite → is a source for (electrolysis of brine, which produces chlorine in fixed proportion) → Sodium hydroxide → is an input to (hot concentrated caustic soda dissolves the aluminium hydroxides) → Bayer process → produces (crystallised from the liquor and calcined, ready for the smelter) → Aluminium oxide → is an input to (dissolved in molten cryolite and electrolysed) → Hall–Héroult process → produces (collects at the cathode while the carbon anodes are consumed) → Aluminium
  • Halite → is an input to (as brine; the salt is the feedstock for both products at once) → Chlor-alkali electrolysis → produces (at the cathode, in fixed proportion to the chlorine whether demand agrees or not) → Sodium hydroxide → is an input to (hot concentrated caustic soda dissolves the aluminium hydroxides) → Bayer process → produces (crystallised from the liquor and calcined, ready for the smelter) → Aluminium oxide → is an input to (dissolved in molten cryolite and electrolysed) → Hall–Héroult process
  • Halite → is a component of (the bulk of most evaporite sequences, and the reason the rock is called salt) → Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the cathode, in fixed proportion to the chlorine whether demand agrees or not) → Sodium hydroxide → is used as (in the Bayer process and in metal cleaning before coating) → Corrosion protection
  • Halite → is an ore of (the same electrolysis; sodium metal is made from molten salt rather than brine) → Sodium → is used as (sodium compounds are among the commonest industrial bases) → Catalysis
  • Halite → is an ore of (by electrolysis of brine, which yields chlorine and sodium hydroxide together) → Chlorine → is used as (chlor-alkali production underpins much of industrial chemistry) → Catalysis

These are the most distinct paths onward. Halite ends up in others besides.