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Material World
Mineral · CaSO4·2H2O

Gypsum

A soft sulfate mineral that gives up its water when gently heated and takes it back on mixing — the basis of plaster.

Gypsum is calcium sulfate with water built into its crystal structure, and that water is the entire point. Heat gypsum gently and it gives up most of it, becoming the powder sold as plaster of Paris. Add water back and the powder recrystallises into interlocking needles, setting hard in minutes.

The reaction is reversible, cheap, and happens at a temperature a wood fire can reach — which is why plaster is one of the oldest manufactured building materials, and why it remains the lining of most interior walls built today.

How to identify it

It is the softest common mineral: a fingernail scratches it easily, and it defines hardness 2 on the Mohs scale. That alone separates it from calcite, which it otherwise resembles, and calcite fizzes in acid where gypsum does not.

It takes three distinctive forms. Selenite is clear and splits into flexible-looking sheets; satin spar is fibrous with a silky sheen; alabaster is fine-grained and massive, soft enough to carve with hand tools, which is why it has been a sculptor's stone since antiquity.

Uses

Plasterboard consumes most gypsum produced. A gypsum core between paper facings makes a wall lining that is fire-resistant — the bound water absorbs heat as it is driven off, and a plasterboard partition buys time in a fire for exactly that reason.

Gypsum is also added to Portland cement, where a few per cent slows the setting reaction enough to make the concrete workable. Without it cement would flash-set in the mixer. Agricultural gypsum conditions heavy soils, and alabaster remains a carving stone.

How it forms

Gypsum is an evaporite: it precipitates when seawater or a saline lake evaporates, and it comes out of solution before halite does, so gypsum beds commonly underlie rock salt in the same sequence.

That origin means it occurs in thick, laterally extensive beds that are simple and cheap to quarry. Gypsum also forms where sulfuric acid from oxidising sulfide minerals meets limestone, and enormous selenite crystals have grown in a few water-filled caves where conditions stayed stable for a very long time.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is an input to

  • Calcination process · gently calcined to plaster of Paris, a far lower temperature than lime burning

contains

is used in

  • Construction industry · plasterboard and plaster, and as the set retarder in cement

is a component of

  • Evaporite rock · 5–40% · precipitated early, when the water has reduced to roughly a fifth of its volume

is an alternative to

  • Quicklime compound · as plaster. Lime plaster sets by absorbing carbon dioxide over months and stays permeable and repairable; gypsum sets in an hour and does not — which is why historic masonry must be repaired with the slow one

is a source for

  • Gypsum plaster material · calcined to drive off three quarters of the water, and it takes it back when mixed

is commonly confused with

  • Chalk rock · blackboard and sidewalk chalk have been gypsum since the nineteenth century, because it casts into sticks from a slurry and makes less dust — so the most familiar association with the word is not the rock at all

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
  • COD Advisory Board / Vilnius University · CC0 — contributors place data in the public domain

Questions this page answers

Where it comes from, and what it becomes

Follow Gypsum back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Downstream — what it becomes

  • Gypsum → is an input to (gently calcined to plaster of Paris, a far lower temperature than lime burning) → Calcination → produces (the solid residue once carbon dioxide has been driven off) → Quicklime → is a component of (as calcium oxide within the clinker phases, not as free lime) → Portland cement → is a component of (the binder — the expensive, energy-intensive, chemically active part) → Concrete → is used in (foundations, frames, floors and civil structures) → Construction
  • Gypsum → is a component of (precipitated early, when the water has reduced to roughly a fifth of its volume) → Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the cathode, in fixed proportion to the chlorine whether demand agrees or not) → Sodium hydroxide → is used as (in the Bayer process and in metal cleaning before coating) → Corrosion protection
  • Gypsum → is a source for (calcined to drive off three quarters of the water, and it takes it back when mixed) → Gypsum plaster → is an input to (at around 150 °C, which is driving off water rather than decomposing a carbonate — so no carbon dioxide comes out of the rock) → Calcination → produces (the solid residue once carbon dioxide has been driven off) → Quicklime → is a component of (as calcium oxide within the clinker phases, not as free lime) → Portland cement → is used in → Construction
  • Gypsum → is used in (plasterboard and plaster, and as the set retarder in cement) → Construction
  • Gypsum → is an input to (gently calcined to plaster of Paris, a far lower temperature than lime burning) → Calcination → produces (the solid residue once carbon dioxide has been driven off) → Quicklime → is a component of (as calcium oxide within the clinker phases, not as free lime) → Portland cement → is an input to (the reactive component — everything else in a concrete mix is aggregate, water, or an admixture adjusting how this reaction runs) → Hydration → produces (it does not dry — the calcium silicates react with the mix water and grow an interlocking hydrate gel, which is why it sets under water and must be kept wet to reach strength) → Concrete
  • Gypsum → is a component of (precipitated early, when the water has reduced to roughly a fifth of its volume) → Evaporite → is a source for (mined as rock salt from bedded deposits, or dissolved in place and pumped up as brine — which is what the chemical industry wants anyway) → Salt → is an input to (the largest single use of salt, and the process the whole chlorine and caustic soda industry rests on) → Chlor-alkali electrolysis → produces (at the anode) → Chlorine → is used as (chlor-alkali production underpins much of industrial chemistry) → Catalysis

These are the most distinct paths onward. Gypsum ends up in others besides.