Skip to content
Material World
Compound · WC

Tungsten carbide

Tungsten and carbon in a structure almost as hard as diamond and far tougher — the material nearly every cutting tool has an edge of.

Tungsten carbide is what most things that cut other things are actually made of at the point of contact. It is nearly as hard as diamond, retains that hardness at temperatures that would soften any steel, and is stiff enough that a tool made from it barely deflects under load.

On its own it is also brittle, and a purely brittle cutting tool is useless. What is actually used is cemented carbide: carbide grains bonded together with five to fifteen per cent cobalt, sintered so the metal wets the grains and holds them in a matrix that can absorb a shock. The composite is a genuine engineering achievement — the hardness of a ceramic with enough toughness to be hit.

Uses

Machine tool inserts, drill bits for rock and for masonry, mining pick tips, saw teeth, dies for drawing wire, ball-point pen balls, snow tyre studs, and the surgical and dental instruments where an edge has to last.

It has a well-known second market in jewellery, where its scratch resistance is the selling point and its brittleness the recurring complaint: a carbide ring will not scratch and will shatter if struck hard, which is either a safety feature or a defect depending on who is describing it.

At the industrial scale, carbide is where most of the world's tungsten goes — and much of the world's cobalt binder with it, which quietly ties machine tooling to the same supply question as batteries.

History

It came out of a lamp factory. German researchers at Osram were looking for a cheaper way to draw tungsten filament wire — the diamond dies then in use were expensive — and produced a sintered carbide hard enough to replace them. It was commercialised as Widia, from *wie Diamant*, like diamond.

The consequence was a step change in what machining could do. Cutting speeds rose several-fold over the high-speed steels then standard, and much of twentieth-century manufacturing productivity rests on a material found while trying to make light bulbs more cheaply.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

contains

  • Tungsten element · half the atoms, and most of the mass — carbide is where the majority of the world's tungsten ends up Wikidata
  • Carbon element · the other half of the formula, and what turns a hard metal into a very hard ceramic Wikidata

is used as

  • Abrasive application · and as a cutting material, which is the larger use — carbide holds an edge at temperatures that would anneal any steel

is an alternative to

  • Diamond mineral · as a cutting material: carbide is tougher and far cheaper, diamond is harder and cuts what carbide cannot
  • Osmiridium alloy · as a wear-resistant tip. Carbide replaced it almost everywhere on cost, and osmiridium keeps the places where chemical inertness matters as much as hardness
  • High-speed steel alloy · carbide is harder and cuts faster and shatters when the cut is interrupted; high-speed steel is what survives an imperfect setup, which is most work outside a production shop

succeeded

  • High-speed steel alloy · in high-volume production cutting, where rigidity is available and speed is worth more than toughness

is produced by

  • Calcination process · tungsten powder and carbon reacted at 1,500 °C, then sintered with cobalt as a binder into the tool the trade actually buys

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)

Questions this page answers

Where it comes from, and what it becomes

Follow Tungsten carbide back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Tungsten carbide → is produced by (tungsten powder and carbon reacted at 1,500 °C, then sintered with cobalt as a binder into the tool the trade actually buys) → Calcination → takes as input (heated until the carbonate decomposes to lime and carbon dioxide) → Limestone → is sourced from (precipitated from it, mostly by organisms building shells and skeletons out of dissolved calcium and carbonate) → Seawater → is composed of (about 96.5 per cent by mass — seawater is 3.5 per cent dissolved solids and the rest of it is this) → Water
  • Tungsten carbide → is produced by (tungsten powder and carbon reacted at 1,500 °C, then sintered with cobalt as a binder into the tool the trade actually buys) → Calcination → takes as input (supplies the silica and alumina that combine with lime in the cement kiln) → Clay → is sourced from (clay is chiefly what feldspar becomes when it weathers) → Orthoclase
  • Tungsten carbide → is produced by (tungsten powder and carbon reacted at 1,500 °C, then sintered with cobalt as a binder into the tool the trade actually buys) → Calcination → takes as input (at around 150 °C, which is driving off water rather than decomposing a carbonate — so no carbon dioxide comes out of the rock) → Gypsum plaster → is sourced from (calcined to drive off three quarters of the water, and it takes it back when mixed) → Gypsum
  • Tungsten carbide → is produced by (tungsten powder and carbon reacted at 1,500 °C, then sintered with cobalt as a binder into the tool the trade actually buys) → Calcination → takes as input (gently calcined to plaster of Paris, a far lower temperature than lime burning) → Gypsum
  • Tungsten carbide → is produced by (tungsten powder and carbon reacted at 1,500 °C, then sintered with cobalt as a binder into the tool the trade actually buys) → Calcination → takes as input (heated until the carbonate decomposes to lime and carbon dioxide) → Limestone → is composed of → Calcite
  • Tungsten carbide → is produced by (tungsten powder and carbon reacted at 1,500 °C, then sintered with cobalt as a binder into the tool the trade actually buys) → Calcination → takes as input (heated until the carbonate decomposes to lime and carbon dioxide) → Limestone → is composed of (in young limestone, before conversion to calcite is complete) → Aragonite

These are the most distinct paths back. Tungsten carbide can be traced through others besides.

Downstream — what it becomes

  • Tungsten carbide → is used as (and as a cutting material, which is the larger use — carbide holds an edge at temperatures that would anneal any steel) → Abrasive