Skip to content
Material World
Material · Natural

Clay

Fine-grained weathered rock that is plastic when wet and rock-hard when fired — the oldest manufactured material.

Clay is what feldspar becomes when it weathers. The clay minerals are hydrous aluminium silicates built in sheets, and their extreme fineness plus their plate-like shape is what gives clay its defining behaviour: wet, the plates slide over one another and the mass holds any shape it is pushed into.

Firing makes that shape permanent. Above roughly six hundred degrees the chemically bound water is driven off irreversibly, and the clay minerals break down and begin to fuse. What comes out is ceramic, and it will not turn back into clay however long it is soaked. That irreversibility is why pottery survives in the archaeological record when almost nothing else does.

How it forms

Clay forms by the chemical weathering of silicate rock, principally feldspar, in the presence of water and dissolved carbon dioxide. Where the clay stays where it formed it is called residual, and it tends to be pure and pale — kaolin, the porcelain clay, is the type example.

Where it is carried away by water and redeposited it picks up iron and organic matter, becoming the darker, more plastic, lower-firing clay found in river terraces and used for brick and common pottery. The distinction between the two governs almost everything about how a clay behaves.

Uses

Brick and roof tile consume the greatest tonnage, followed by cement manufacture, where clay supplies the alumina and silica that combine with limestone in the kiln.

Refined clays go into pottery, sanitaryware and porcelain. Kaolin is also used in enormous quantity as a paper coating, giving a smooth printable surface, and as a filler in paint, rubber and pharmaceuticals. Bentonite clay, which swells dramatically in water, is used as a drilling mud, a foundry sand binder and a sealing layer in landfill liners.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is sourced from

  • Orthoclase mineral · clay is chiefly what feldspar becomes when it weathers
  • Plagioclase mineral · plagioclase weathers to clay as readily as potassium feldspar does

is a source for

  • Brick material · formed, dried and fired until the clay minerals break down irreversibly
  • Stoneware material · a clay that survives 1200 °C and above, which an earthenware clay does not
  • Earthenware material · almost any clay, which is why it is the ceramic every early culture reached first
  • Refractory brick material · as fireclay for the general-purpose grades; the basic linings are magnesia and dolomite instead

is used as

  • Refractory lining application · fireclay brick, the oldest and cheapest lining material
  • Glass and ceramics application · the mineral that makes a ceramic shapeable before it is fired, which is the whole basis of pottery

is an input to

  • Calcination process · supplies the silica and alumina that combine with lime in the cement kiln
  • Firing process · shaped and dried, then heated past the point where its minerals break down irreversibly
  • Extrusion process · the standard way a brick is formed before firing: a continuous column pushed through a die and wire-cut into units

is a component of

  • Shale rock · 40–75% · the clay minerals that make up most of the rock, and whose flat particles give it its splitting
  • Porcelain material · 40–60% · kaolin, for the plasticity that lets the body be shaped before firing
  • Bone china material · 20–30% · china clay for the plasticity that lets the body be formed at all — bone ash has none, and a body of bone ash alone could not be thrown or cast

is an alternative to

  • Talc mineral · as a mineral filler in paper, paint and plastic, where the choice is between talc's platy particles and kaolin's stacked ones, and both are being bought for opacity per tonne

is used in

  • Pencil object · mixed with the graphite and fired, and the ratio is the grade: more clay is harder and lighter, which is what H means

Sources

  • Material World
    Our own writing

Questions this page answers

Where it comes from, and what it becomes

Follow Clay back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Clay → is sourced from (clay is chiefly what feldspar becomes when it weathers) → Orthoclase
  • Clay → is sourced from (plagioclase weathers to clay as readily as potassium feldspar does) → Plagioclase

Downstream — what it becomes

  • Clay → is a component of (the clay minerals that make up most of the rock, and whose flat particles give it its splitting) → Shale → is a source for (slate is shale taken further: the clay rebuilt as mica and aligned by pressure, cleaving across the original bedding rather than along it) → Slate → is a source for (for roofing and flooring rather than walling) → Dimension stone → is used in (quarried rather than mined, and the distinction is legal and technical rather than merely a word) → Mining and quarrying → is associated with (steam pumping allowed mines below the water table, which is what made deep coal possible) → Industrial Revolution complete chain
  • Clay → is an input to (supplies the silica and alumina that combine with lime in the cement kiln) → Calcination → produces (the solid residue once carbon dioxide has been driven off) → Quicklime → is a component of (as calcium oxide within the clinker phases, not as free lime) → Portland cement → is a component of (the binder — the expensive, energy-intensive, chemically active part) → Concrete → is used in (foundations, frames, floors and civil structures) → Construction
  • Clay → is a source for (a clay that survives 1200 °C and above, which an earthenware clay does not) → Stoneware → is an input to (to 1200–1300 °C, which is the vitrification that separates it from earthenware — and it is a temperature rather than a recipe) → Firing → produces (as sintering, from refined powders rather than clay) → Technical ceramic → is used in (the honeycomb monolith the metals are dispersed across, which supplies the surface area and survives the thermal cycling) → Catalytic converter → is used as (the largest catalytic application by metal value there is) → Catalysis
  • Clay → is a source for (almost any clay, which is why it is the ceramic every early culture reached first) → Earthenware → is an input to (to 1000–1150 °C, below vitrification, which is why it stays porous and why it was achievable before anybody could build a hotter kiln) → Firing → produces (as sintering, from refined powders rather than clay) → Technical ceramic → is used in (the honeycomb monolith the metals are dispersed across, which supplies the surface area and survives the thermal cycling) → Catalytic converter → is used as (the largest catalytic application by metal value there is) → Catalysis
  • Clay → is a source for (as fireclay for the general-purpose grades; the basic linings are magnesia and dolomite instead) → Refractory brick → is an input to (or installed unfired as a monolithic castable and cured by the furnace's own first heat) → Firing → produces (as sintering, from refined powders rather than clay) → Technical ceramic → is used in (the honeycomb monolith the metals are dispersed across, which supplies the surface area and survives the thermal cycling) → Catalytic converter → is used as (the largest catalytic application by metal value there is) → Catalysis
  • Clay → is an input to (shaped and dried, then heated past the point where its minerals break down irreversibly) → Firing → produces (as sintering, from refined powders rather than clay) → Technical ceramic → is used in (the honeycomb monolith the metals are dispersed across, which supplies the surface area and survives the thermal cycling) → Catalytic converter → is used as (the largest catalytic application by metal value there is) → Catalysis

These are the most distinct paths onward. Clay ends up in others besides.