Chalk
A limestone made almost entirely of microscopic algal plates — soft, porous, white, and not what a blackboard stick is made of.
Chalk is a limestone, and an unusually pure one: 95 per cent or more calcium carbonate, laid down in warm shallow seas in the Late Cretaceous — a period named after it, from creta, the Latin for chalk.
What makes it chalk rather than any other limestone is what the grains are. Almost the whole rock is coccoliths: interlocking calcite plates a few micrometres across, secreted by single-celled algae and shed continuously as they lived and died. A chalk cliff is a hundred metres of the skeletons of organisms too small to see, accumulated over tens of millions of years at a few centimetres a millennium.
It is soft, very porous, and permeable enough to be a major aquifer — the chalk under southeast England supplies a large share of its water, and the same porosity is why chalk landscapes have dry valleys and few surface streams.
How to identify it
The most useful thing to know about chalk is that the stick sold as chalk is not chalk.
Blackboard chalk has been made from gypsum — calcium sulfate — since the nineteenth century, because gypsum can be cast into sticks from a slurry and writes with less dust. Sidewalk chalk is the same. So a schoolroom association that seems to be about a rock is about a different mineral entirely, and the words have simply come apart.
Genuine chalk in the ground is unmistakable: it is white, it marks your hand, it is soft enough to scratch with a fingernail, and it fizzes vigorously in dilute acid, which gypsum does not.
The flint is the other tell. Chalk beds carry nodules and bands of flint through them — silica from sponge spicules dissolved and reprecipitated in the sediment — and a white cliff with dark knobbly seams running horizontally through it is chalk and nothing else.
Uses
Ground and purified, chalk becomes whiting, and whiting is one of the most widely used industrial fillers there is: in paint as an extender, in paper as both filler and coating, in PVC and rubber to add bulk and stiffness, in putty, in toothpaste as the mild abrasive, and as the calcium supplement in animal feed.
Burned, it is a source of lime in the same way any limestone is, and chalk-derived lime went into mortar across the regions where chalk is what there is.
Agriculturally it is spread to raise soil pH, which is the oldest recorded use of any rock as a soil amendment.
And its structural role is as an aquifer rather than as a material: the chalk of the Paris and London basins stores and transmits water on a scale that shapes where the water in those cities comes from.
Cultural significance
The White Cliffs of Dover are chalk, and so is the corresponding coast at Cap Blanc-Nez across the Channel — the same bed, cut through by the breach that separated Britain from the continent, which is why the two coasts look alike.
Because chalk is soft and the turf over it is thin, cutting a figure through the turf exposes brilliant white underneath and leaves a hill figure that lasts as long as somebody keeps scouring it. The Uffington White Horse is Bronze Age and has been maintained for something like three thousand years, which makes it one of the longest continuously performed maintenance tasks anywhere.
How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.
How this connects
Where a connection has been confirmed by an outside reference, that reference is named beside it.
is composed of
- Calcite — mineral · 90–99% · 95 per cent or more, and almost all of it as coccoliths — interlocking calcite plates a few micrometres across, secreted by single-celled algae
is sourced from
- Seawater — material · built from dissolved calcium and carbonate by algae in warm shallow Cretaceous seas, and accumulated at a few centimetres a millennium
belongs to the group
- Limestone — rock · chalk is a limestone — an unusually pure and unusually porous one, distinguished by what its grains are rather than by what it is made of
is an input to
- Calcination — process · burned to quicklime exactly as any limestone is, and it was the lime of the regions where chalk is what the ground is made of
is used as
- Pigment — application · as whiting — ground and washed chalk, used as an extender in paint, a filler in paper and PVC, and the mild abrasive in toothpaste
is commonly confused with
- Gypsum — mineral · blackboard and sidewalk chalk have been gypsum since the nineteenth century, because it casts into sticks from a slurry and makes less dust — so the most familiar association with the word is not the rock at all
contains
- Calcium — element · as the carbonate that is nearly the whole rock
is an alternative to
- Limestone — rock · as a lime and cement feedstock, where the choice is entirely local: chalk is softer and cheaper to quarry, and too weak and porous to be a building stone
Sources
- Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
- Material WorldOur own writing