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Material World
Mineral · HgS

Cinnabar

Mercury sulfide — the only ore of mercury worth mining, and the source of vermilion, the most brilliant red available to painters for two thousand years.

Ore Pigment

Cinnabar is mercury sulfide, and it is unusual among ores in giving up its metal almost trivially: roast it in air and the mercury leaves as vapour, to be condensed as a liquid metal. That simplicity is why mercury was known and used in antiquity when far more abundant metals were not.

It is also the source of vermilion. Ground cinnabar gives a red of a saturation nothing else could match before synthetic pigments, and it was used from Roman wall painting through to the illuminated manuscript and the Chinese lacquer tradition.

How to identify it

The scarlet streak is decisive and separates cinnabar from every other red mineral — hematite's streak is a duller red-brown, and realgar's is orange. Cinnabar is also very heavy for a soft mineral, at around eight times the density of water and a hardness of only 2 to 2.5.

Environmental impact

The mineral itself is poorly soluble and comparatively inert; the hazard is what is done to it. Roasting releases mercury vapour, and historic mining districts — Almadén above all, worked for two thousand years — carry mercury contamination that will outlast any remediation planned for it.

Mercury's toxicity was understood early and the mines were worked by forced labour for much of their history, which makes cinnabar one of the clearer cases of a material whose cost was paid by people who had no say in it.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is an ore of

  • Mercury element · essentially the only ore; roasting it in air releases the metal as vapour, which is condensed Wikidata

is an input to

  • Roasting process · roasted in air; the mercury leaves as vapour rather than staying behind as an oxide

is a component of

  • Epithermal vein deposit type · at the top of the sequence, mercury being volatile enough to travel furthest before the fluid drops it

contains

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
  • COD Advisory Board / Vilnius University · CC0 — contributors place data in the public domain

Questions this page answers

Where it comes from, and what it becomes

Follow Cinnabar back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Downstream — what it becomes

  • Cinnabar → is an input to (roasted in air; the mercury leaves as vapour rather than staying behind as an oxide) → Roasting → produces (as the oxide, which is then reduced — roasting is the step that makes zinc sulfide smeltable) → Zinc → is an input to (the addition that makes brass; it boils below copper's melting point, which is the difficulty) → Alloying and melting → produces (zinc dissolved into molten copper, under conditions that stop the zinc boiling off) → Brass → is used as (in air rather than seawater — brass dezincifies in chloride) → Corrosion protection
  • Cinnabar → is an ore of (essentially the only ore; roasting it in air releases the metal as vapour, which is condensed) → Mercury → is used as (the vapour discharge in fluorescent tubes, now being phased out) → Lighting
  • Cinnabar → is a component of (at the top of the sequence, mercury being volatile enough to travel furthest before the fluid drops it) → Epithermal vein
  • Cinnabar → is an ore of (essentially the only ore; roasting it in air releases the metal as vapour, which is condensed) → Mercury → is a component of (the defining constituent — an amalgam is by definition mercury with something dissolved in it) → Amalgam
  • Cinnabar → is an input to (roasted in air; the mercury leaves as vapour rather than staying behind as an oxide) → Roasting → produces (as the oxide, which is then reduced — roasting is the step that makes zinc sulfide smeltable) → Zinc → is a source for (recovered almost entirely from zinc refining, so indium supply is set by zinc demand) → Indium → is used as (as the transparent electrode in displays) → Lighting
  • Cinnabar → is an input to (roasted in air; the mercury leaves as vapour rather than staying behind as an oxide) → Roasting → produces (as the oxide, which is then reduced — roasting is the step that makes zinc sulfide smeltable) → Zinc → is a source for (captured from the flue dusts of zinc smelting before it disperses) → Thallium → is used as (thallium-201 as a cardiac imaging tracer) → Medical imaging

These are the most distinct paths onward. Cinnabar ends up in others besides.