Monazite
A rare earth phosphate that carries thorium with it — the other major rare earth ore, and the reason their processing leaves radioactive residues.
Monazite is a phosphate of the light rare earths, written with cerium, lanthanum and neodymium bracketed together because the mineral takes whichever is available. Alongside bastnäsite it is one of the two ores the world's rare earths come from.
What distinguishes it is thorium. The thorium ion is close enough in size and charge to the rare earths to substitute into the same site, so monazite is radioactive — mildly, but enough that its residues are regulated as radioactive waste. That is not a detail. It is a large part of why rare earth separation is concentrated in so few countries, and why reopening capacity elsewhere has proved slower than opening mines.
Extraction
Monazite is chemically tough and physically dense, so it survives weathering and transport and accumulates in heavy mineral sands with zircon, rutile and ilmenite. Much of it is recovered as a by-product of mining those sands for titanium.
That co-occurrence means monazite is often produced whether or not anybody wants it, and stockpiles accumulate where the thorium makes disposal awkward and processing unattractive.
How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.
How this connects
Where a connection has been confirmed by an outside reference, that reference is named beside it.
is an ore of
is an input to
- Rare earth separation — process · the other feed alongside bastnäsite, bringing thorium into the residues with it
is a component of
- Pegmatite — rock · an accessory of rare-element pegmatites rather than a defining constituent — carrying the light rare earths and the thorium with them
- Carbonatite — rock · the rare earth phosphate, carrying thorium with it — which is the difficulty rather than the resource
- Granite — rock · in the more evolved granites, carrying the light rare earths and the thorium that goes with them
is a source for
- Mischmetal — alloy · reduced from the mixed light rare earths that monazite and bastnäsite deliver, in the proportions the ore happened to contain
is an alternative to
- Bastnäsite — mineral · as light rare earth ore, and the deciding factor is thorium: monazite carries enough to make the residue a radioactive waste problem and bastnäsite carries far less, which is why the large operations are bastnäsite and monazite is mostly a by-product
contains
- Cerium — element · substitutes within a solid solution — an individual specimen may hold little of it
- Lanthanum — element · substitutes within a solid solution — an individual specimen may hold little of it
- Neodymium — element · substitutes within a solid solution — an individual specimen may hold little of it
- Oxygen — element
- Phosphorus — element
- Thorium — element · substitutes within a solid solution — an individual specimen may hold little of it
Sources
- Material WorldOur own writing
- Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)