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Element · La

Lanthanum

The first of the lanthanides, and the element that made nickel-metal-hydride batteries and modern oil refining work.

Lanthanum gives its name to the lanthanide series and is one of the more abundant rare earths, despite the name of the group. It is soft, reactive and oxidises rapidly in air, so it is stored under oil or in an inert atmosphere.

Its industrial significance is easy to miss because it works inside things. Lanthanum compounds are the active component of the fluid catalytic cracking catalysts that convert heavy petroleum fractions into petrol and diesel, a process that underlies most of the world's transport fuel supply.

Uses

Fluid catalytic cracking is the largest use by tonnage, and refineries consume lanthanum continuously as the catalyst is replaced.

Lanthanum-nickel alloys absorb hydrogen reversibly and were the basis of nickel-metal-hydride batteries, which powered the first generation of hybrid cars. Lanthanum oxide raises the refractive index of optical glass, so it appears in camera lenses. Lanthanum carbonate is a prescribed medicine that binds excess phosphate in patients with kidney failure, and lanthanum is a component of mischmetal lighter flints.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

is used as

  • Catalysis application · fluid catalytic cracking, which underlies most transport fuel supply

is produced by

  • Rare earth separation process · a light rare earth, separated from its neighbours by countercurrent solvent extraction

is a component of

  • Mischmetal alloy · 20–30% · roughly a quarter, again as the ore gave it

is found in

  • Bastnäsite mineral · substitutes within a solid solution — an individual specimen may hold little of it
  • Monazite mineral · substitutes within a solid solution — an individual specimen may hold little of it

Sources

  • Material World
    Our own writing
  • Wikimedia Foundation · Creative Commons CC0 1.0 Universal (public domain dedication)
  • US National Library of Medicine · Mixed — aggregated third-party content, rights retained by depositors
  • United States Department of Commerce · US Government work — public information, credit requested

Questions this page answers

Where it comes from, and what it becomes

Follow Lanthanum back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Lanthanum → is produced by (a light rare earth, separated from its neighbours by countercurrent solvent extraction) → Rare earth separation → takes as input (the principal ore of the light rare earths, carrying all of them together) → Bastnäsite
  • Lanthanum → is produced by (a light rare earth, separated from its neighbours by countercurrent solvent extraction) → Rare earth separation → takes as input (the other feed alongside bastnäsite, bringing thorium into the residues with it) → Monazite
  • Lanthanum → is produced by (a light rare earth, separated from its neighbours by countercurrent solvent extraction) → Rare earth separation → takes as input (the heavy rare earth feed, where monazite and bastnäsite bring the light ones) → Xenotime

Downstream — what it becomes

  • Lanthanum → is a component of (roughly a quarter, again as the ore gave it) → Mischmetal → is used as (added to molten steel to scavenge sulfur and oxygen and reshape the inclusions that remain, which improves toughness — an unglamorous use that consumes a great deal of it) → Alloying
  • Lanthanum → is used as (fluid catalytic cracking, which underlies most transport fuel supply) → Catalysis
  • Lanthanum → is a component of (roughly a quarter, again as the ore gave it) → Mischmetal → is used as (the negative electrode of the nickel-metal hydride battery, which powered hybrid vehicles and portable electronics before lithium-ion displaced it) → Battery electrodes