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Material World
Compound · H2SO4

Sulfuric acid

The most-produced industrial chemical in the world, and a reasonable proxy for a country's industrial output.

Sulfuric acid is made in greater quantity than any other chemical, and almost none of it is sold to the public. It is an intermediate: something consumed inside industrial processes to make other things, which is why its production statistics track industrial activity so closely that economists have used them as an index.

Its dangerous reputation is deserved but often misattributed. Concentrated sulfuric acid harms mainly by dehydration rather than by acidity — it strips water out of organic matter, which is why it chars sugar and paper and why the burns it causes are severe. Diluting it releases a great deal of heat, which is why acid is added to water and never the reverse.

Processing

Made by the contact process. Sulfur — increasingly recovered from oil and gas processing rather than mined — is burned to sulfur dioxide, which is then oxidised to sulfur trioxide over a vanadium pentoxide catalyst.

The last step is counter-intuitive: sulfur trioxide is not added to water, because the reaction is so violent it produces an unmanageable mist. It is absorbed into existing concentrated sulfuric acid to make oleum, and the oleum is then diluted. A plant is built around handling that exotherm.

Uses

Fertiliser dominates. Most sulfuric acid is used to treat phosphate rock to make phosphoric acid and superphosphate, which is to say most of it ends up growing food.

Beyond that: leaching copper, zinc and uranium from low-grade ores; pickling steel to remove scale before rolling or coating; refining petroleum; making detergents, dyes and explosives; and serving as the electrolyte in lead-acid batteries, which is the one form most people ever handle.

Medium confidence Weak evidence

How we know: checked recently · only one source, so there is nothing to cross-check it against · stated directly by the source.

How this connects

Where a connection has been confirmed by an outside reference, that reference is named beside it.

contains

is sourced from

  • Sulfur element · burned to sulfur dioxide, oxidised, then absorbed — the contact process

is used as

  • Fertiliser application · treating phosphate rock to make phosphoric acid and superphosphate

is produced by

  • Contact process process · absorbed into existing acid as oleum, then diluted — never added to water directly

is used in

  • Chemical manufacture industry · produced in greater tonnage than any other manufactured chemical, and a country's consumption of it was once used as an index of its industrial development

Sources

  • Material World
    Our own writing
  • US National Library of Medicine · Mixed — aggregated third-party content, rights retained by depositors

Questions this page answers

Where it comes from, and what it becomes

Follow Sulfuric acid back to what it starts as, and forward into what it becomes. Each step is a documented one — a real route material takes, not a chain of inference.

Upstream — what it comes from

  • Sulfuric acid → is produced by (absorbed into existing acid as oleum, then diluted — never added to water directly) → Contact process → takes as input (burned to sulfur dioxide, increasingly recovered from oil and gas rather than mined — and including the sulfur dioxide captured from ore roasting, which turns a smelter's principal pollutant into a feedstock) → Sulfur → is extracted from (historically the principal source of sulfur for sulfuric acid) → Pyrite
  • Sulfuric acid → is sourced from (burned to sulfur dioxide, oxidised, then absorbed — the contact process) → Sulfur → is extracted from (historically the principal source of sulfur for sulfuric acid) → Pyrite
  • Sulfuric acid → is sourced from (burned to sulfur dioxide, oxidised, then absorbed — the contact process) → Sulfur → is produced by (recovered from the hydrogen sulfide stripped out of natural gas and crude oil — which is now almost the whole of world supply) → Claus process
  • Sulfuric acid → is produced by (absorbed into existing acid as oleum, then diluted — never added to water directly) → Contact process → takes as input (burned to sulfur dioxide, increasingly recovered from oil and gas rather than mined — and including the sulfur dioxide captured from ore roasting, which turns a smelter's principal pollutant into a feedstock) → Sulfur → is produced by (recovered from the hydrogen sulfide stripped out of natural gas and crude oil — which is now almost the whole of world supply) → Claus process

Downstream — what it becomes

  • Sulfuric acid → is used as (treating phosphate rock to make phosphoric acid and superphosphate) → Fertiliser
  • Sulfuric acid → is used in (produced in greater tonnage than any other manufactured chemical, and a country's consumption of it was once used as an index of its industrial development) → Chemical manufacture