Semiconductor
A semiconductor is a material whose conductivity can be controlled — by doping it, by illuminating it, or by applying a field to it — and that controllability is the whole of its usefulness. Its own conductivity, which is poor, is beside the point.
Silicon dominates and is not the best of these at anything electrical. It won because it forms a stable, adherent, insulating native oxide, which is what makes the planar process possible. The compound semiconductors here exist where silicon's band gap or carrier mobility is the limit — light emission, high frequency, high power.
Compound
Cadmium telluride
with a band gap of about 1.5 eV, close to the theoretical optimum for converting sunlight
Compound
Gallium arsenide
direct band gap, which is what lets it emit light — the property silicon fundamentally lacks
Compound
Gallium nitride
with a band gap of 3.4 electron volts against silicon's 1.1 — which is what puts blue light and high-voltage switching within reach and puts both out of silicon's
Material
Polysilicon
and the purity is the product: at these levels an unwanted atom in a billion measurably shortens the carrier lifetime
Element
Silicon
The second most abundant element in the Earth's crust, and the substrate of essentially all modern electronics.
Each of these uses is established and cited on its own. Whether something counts as an ore, for instance, depends on grade, price and era — and those qualifications are shown alongside it.